----------------------------------------------------------------------- SEMINAR OF THE LABORATORY FOR COMPUTER DESIGN OF MATERIALS Institute for Computational Sciences and Informatics CSI 929 (http://science.gmu.edu/physics) ----------------------------------------------------------------------- Exciton Calculations in Semiconductor Quantum Wells, Wires, and Dots Scott N. Walck Naval Research Laboratory Washington D. C. Excitons, or electron-hole pairs, play a central role in the optical properties of semiconductors, and their influence is even more pronounced in confined geometries such as quantum wells, wires, and dots. We calculate energies and wavefunctions for excitons in these types of environments. The exciton is described in the effective-mass approximation by a two-body Hamiltonian which includes the electron confinement, the hole confinement, and the electron-hole interaction. Exciton binding energies are calculated using variational techniques for quantum wells, rectangular quantum wires, and cylindrical quantum dots. These particular geometries have been the subject of a systematic experimental investigation of the effect of confinement and reduced dimensionality by our collaborators. Their experiments provide an indirect measure of binding energy as a function of nanostructure feature size, and the agreement between theory and experiment is very good. The effects of an external magnetic field on quantum-confined excitons are also an area of current investigation. In these calculations, the "p-like" character of states at the top of the valence-band is important. A formalism is used to calculate exciton energies and wavefunctions in which the hole is described by the so-called Luttinger Hamiltonian. Monday , February 12 1996 5:00 pm Room 206, Science & Tech. I -------------------------------------------------------------------